KYIV, Ukraine >> Russian forces shelled Ukraine’s second-largest city today, rocking a residential neighborhood, and closed in on the capital, Kyiv, in a 17-mile convoy of hundreds of tanks and other vehicles, as talks aimed at stopping the fighting yielded only an agreement to keep talking.

Amid ever-growing international condemnation, Russia found itself increasingly isolated five days into its invasion, while also facing unexpectedly fierce resistance on the ground in Ukraine and economic havoc at home.

For the second day in a row, the Kremlin raised the specter of nuclear war, announcing that its nuclear-capable intercontinental ballistic missiles, submarines and long-range bombers had all been put on high alert, following President Vladimir Putin’s orders over the weekend.

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Stepping up his rhetoric, Putin denounced the U.S. and its allies as an “empire of lies.”

Meanwhile, an embattled Ukraine moved to solidify its ties to the West by applying to join the European Union — a largely symbolic move for now, but one that is unlikely to sit well with Putin, who has long accused the U.S. of trying to pull Ukraine out of Moscow’s orbit.

A top Putin aide and head of the Russian delegation, Vladimir Medinsky, said that the first talks held between the two sides since the invasion lasted nearly five hours and that the envoys “found certain points on which common positions could be foreseen.” He said they agreed to continue the discussions in the coming days.

As the talks along the Belarusian border wrapped up, several blasts could be heard in Kyiv, and Russian troops advanced on the city of nearly 3 million. The vast convoy of armored vehicles, tanks, artillery and support vehicles was 17 miles (25 kilometers) from the center of the city, according to satellite imagery from Maxar Technologies.

People in Kyiv lined up for groceries after the end of a weekend curfew, standing beneath a building with a gaping hole blown in its side.

Messages aimed at the advancing Russian soldiers popped up on billboards, bus stops and electronic traffic signs across the capital. Some used profanity to encourage Russians to leave. Others appealed to their humanity.

“Russian soldier — Stop! Remember your family. Go home with a clean conscience,” one read.

Video from Kharkiv, Ukraine’s second-biggest city, with a population of about 1.5 million, showed residential areas being shelled, with apartment buildings shaken by repeated, powerful blasts. Flashes of fire and gray plumes of smoke could be seen.

Footage released by the government from Kharkiv depicted what appeared to be a home with water gushing from a pierced ceiling. What looked like an undetonated projectile was on the floor.

Authorities in Kharkiv said at least seven people had been killed and dozens injured. They warned that casualties could be far higher.

“They wanted to have a blitzkrieg, but it failed, so they act this way,” said 83-year-old Valentin Petrovich, who watched the shelling from his downtown apartment and gave just his first name and his Russian-style middle name out of fear for his safety.

The Russian military has denied targeting residential areas despite abundant evidence of shelling of homes, schools and hospitals.

Fighting raged in other towns and cities across the country. The strategic port city of Mariupol, on the Sea of Azov, is “hanging on,” said Zelenskyy adviser Oleksiy Arestovich. An oil depot was reported bombed in the eastern city of Sumy.

In the seaside resort town of Berdyansk, dozens of protesters chanted angrily in the main square against Russian occupiers, yelling at them to go home and singing the Ukrainian national anthem. They described the soldiers as exhausted young conscripts.

“Frightened kids, frightened looks. They want to eat,” Konstantin Maloletka, who runs a small shop, said by telephone. He said the soldiers went into a supermarket and grabbed canned meat, vodka and cigarettes.

“They ate right in the store,” he said. “It looked like they haven’t been fed in recent days.”

Across Ukraine, terrified families huddled overnight in shelters, basements or corridors.

“I sit and pray for these negotiations to end successfully, so that they reach an agreement to end the slaughter,” said Alexandra Mikhailova, weeping as she clutched her cat in a shelter in Mariupol. Around her, parents tried to console children and keep them warm.

For many, Russia’s announcement of a nuclear high alert stirred fears that the West could be drawn into direct conflict with Russia. But a senior U.S. defense official, speaking on condition of anonymity, said the United States had yet to see any appreciable change in Russia’s nuclear posture.

As far-reaching Western sanctions on Russian banks and other institutions took hold, the ruble plummeted, and Russia’s Central Bank scrambled to shore it up, as did Putin, signing a decree restricting foreign currency.

But that did little to calm Russian fears. In Moscow, people lined up to withdraw cash as the sanctions threatened to drive up prices and reduce the standard of living for millions of ordinary Russians.

In yet another blow to Russia’s economy, oil giant Shell said it is pulling out of the country because of the invasion. It announced it will withdraw from its joint ventures with state-owned gas company Gazprom and other entities and end its involvement in the Nord Stream 2 pipeline project between Russia and Europe.

The economic sanctions, ordered by the U.S. and other allies, were just one contributor to Russia’s growing status as a pariah country.

Russian airliners are banned from European airspace, Russian media is restricted in some countries, and some high-tech products can no longer be exported to the country. Today, in a major blow to a soccer-mad nation, Russian teams were suspended from all international soccer.

In other developments:

— The chief prosecutor of the International Criminal Court said he will open an investigation soon into possible war crimes and crimes against humanity in Ukraine.

— Cyberattacks hit Ukrainian embassies around the world, and Russian media outlets.

— The United States announced it is expelling 12 members of Russia’s U.N. mission, accusing them of spying.

— The 193-nation U.N. General Assembly opened its first emergency session in decades, with Assembly President Abdulla Shahid calling for an immediate cease-fire and “a full return to diplomacy and dialogue.”

The U.N. human rights chief said at least 102 civilians have been killed and hundreds wounded — warning that figure is probably a vast undercount — and Ukraine’s president said at least 16 children were among the dead.

More than a half-million people have fled the country since the invasion, another U.N. official said, many of them going to Poland, Romania and Hungary.

Among the refugees in Hungary was Maria Pavlushko, 24, an information technology project manager from a city west of Kyiv. She said her father stayed behind to fight the Russians.

“I am proud about him,” she said, adding that many of her friends were planning to fight too.

The negotiators at today’s talks met at a long table with the blue-and-yellow Ukrainian flag on one side and the Russian tricolor on the other.

But while Ukraine sent its defense minister and other top officials, the Russian delegation was led by Putin’s adviser on culture — an unlikely envoy for ending a war and perhaps a sign of how seriously Moscow took the talks.

It wasn’t immediately clear what Putin is seeking in the talks, or from the war itself, though Western officials believe he wants to overthrow Ukraine’s government and replace it with a regime of his own, reviving Moscow’s Cold War-era influence.

At this stage, Ukraine is many years away from reaching the standards for achieving EU membership. Any addition to the 27-nation bloc must be approved unanimously by its members, and Ukraine’s deep-seated corruption could make it hard for the country to win acceptance.

Still, in an interview with Euronews on Sunday, EU Commission chief Ursula von der Leyen said: “We want them in the European Union.”